By Yury Gogotsi and Volker Presser
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131,135–138 For the two basic shapes of graphene edges, armchair and zigzag edges, it has been shown that graphitic networks with zigzag edges have a localized edge state at the Fermi level which armchair edges do not have. 14 Armchair (a) and zigzag (b) edges in graphene. (With permission from Koskinen, P. , Phys. Rev. ) 23 Graphene Theoretical predictions and experimental observations have clarified that the electronic structure in graphene strongly depends on the geometry of edges, especially when the flake size is in a nanometer scale because a large fraction of carbon atoms sit on its edge.
Carbon, 38, 241, 2000; Xu, Z. , ACS Nano, 5, 2908, 2011. ) (d) Functionalization of GO by isocyanates that can interact with both carboxyl and hydroxyl groups. (From Stankovich, S.
9). In this method, arc-grown MWCNTs are partially embedded in a polymer film and are etched selectively with Ar plasma. The film is then removed using solvent vapor followed by heat treatment of the resulting nanoribbons to remove any residue. This technique can create very narrow graphene nanoribbons (<10 nm) which exhibit semiconductor behavior. 110 c. Intercalation exfoliation. 111 In this method, after dispersion of CNTs in dry tetrahydrofuran by sonication, the dispersion was added into liquid NH3, and Li was then added into the liquid in a 10:1 Li:C weight ratio.