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Surface tension measurements make it possible to calculate, from the Gibbs isotherm, the surface excess of substance B, which is a relative quantity. , hydrocarbon phase (or oil phase) is used to modify the interactions between molecules in a spread film of investigated longchain substances [6,15,17,18]. , interactions between adsorbed molecules due to dipole and van der Waals forces) is negligible. Thus, at the oil–water interfaces behavior of adsorbates is much closer to ideal, but quantitative interpretation may be uncertain, in particular for the higher chains which are predominantly dissolved in the oil phase to an unknown activity.

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