By Henning Hopf, Michael S. Sherburn
Filling a spot available in the market, this guide offers a accomplished evaluate of the interesting and increasing box of cross-conjugated molecules, their chemistry, synthesis and houses.
The editor is without doubt one of the world's prime scientists within the box, and has assembled right here a crew of specialists to debate diverse periods of molecules, in addition to using cross-conjugation for natural synthesis and purposes in digital platforms and fabric technological know-how
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34) . A variety of diﬀerent carbamates 213 successfully underwent Rh(III)-catalyzed C–H activation and coupling to generate cyclic and acyclic substituted dendralenes 214. While the general route works quite well between the tri-substituted allene and acyclic carbamates, the reaction is not high yielding if the enol ester is cyclic or the allene is mono- or tetra-substituted. 34 Rh(III)-catalyzed C–H activations of carbamates by Fu and coworkers . 35) . A stable dendralene intermediate 217 was prepared from substituted phenol 215 and allene 216, as an intermediate in the Rh(III)-catalyzed synthesis of 2H-chromenes.